A ternary supramolecular system containing a boronated DNA-metallointercalator, β-cyclodextrin and the hexanucleotide d(GTCGAC)2.

نویسندگان

  • H Y Vincent Ching
  • Damian P Buck
  • Mohan Bhadbhade
  • J Grant Collins
  • Louis M Rendina
چکیده

Solution NMR studies of the interaction between the hexanucleotide d(GTCGAC)(2), β-cyclodextrin and a boronated 2,2':6',2''-terpyridineplatinum(II) complex containing 1,12-dicarba-closo-dodecaborane(12) (1,12-closo-carborane) reveal the formation of a remarkable ternary supramolecular system in which the terpyridine ligand is intercalated between the C(3) and G(4) bases, whilst the closo-carborane moiety is encapsulated by the cyclic sugar.

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عنوان ژورنال:
  • Chemical communications

دوره 48 6  شماره 

صفحات  -

تاریخ انتشار 2012